Bis(2,2′-bipyridyl-κ2 N,N′)chloridonickel(II) nitrate trihydrate
نویسندگان
چکیده
In the title hydrated salt, [NiCl(C10H8N2)2](NO3)·3H2O, the Ni(2+) ion is coordinated by two 2,2'-bipyridyl (2,2'-bpy) ligands and a chloride ion in a trigonal-bipyramidal geometry. The chloride ion occupies an equatorial site and the dihedral angle between the 2,2'-bpy ring systems is 72.02 (6)°. In the crystal, the components are linked by C-H⋯O and O-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions [shortest centroid-centroid separation = 3.635 (2) Å], generating a three-dimensional network.
منابع مشابه
Bis(2,2′-bipyridyl-κ2 N,N′)(carbonato-κ2 O,O′)cobalt(III) bromide trihydrate
The title complex, [Co(CO(3))(C(10)H(8)N(2))(2)]Br·3H(2)O, is isostructural with the chloride analogue. The six-coordinated octahedral [Co(2,2'-bipy)(2)CO(3)](+) cation (2,2'-bipy is 2,2'-bipyrid-yl), bromide ion and water mol-ecules are linked together via O-H⋯Br and O-H⋯O hydrogen bonds, generating a one-dimensional chain.
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عنوان ژورنال:
دوره 70 شماره
صفحات -
تاریخ انتشار 2014